Strontium sulfate
Names | |
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IUPAC name
Strontium sulfate | |
Other names | |
Identifiers | |
7759-02-6 | |
3D model (Jmol) | Interactive image |
ChemSpider | 2341151 |
ECHA InfoCard | 100.028.955 |
EC Number | 231-850-2 |
PubChem | 3084026 |
UNII | 7Q3KX2L47F |
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Properties | |
SrSO4 | |
Molar mass | 183.68 g/mol |
Appearance | white orthorhombic crystals |
Density | 3.96 g/cm3 |
Melting point | 1,606 °C (2,923 °F; 1,879 K) |
0.0135 g/100 mL (25 °C) 0.014 g/100 mL (30 °C) | |
Solubility product (Ksp) |
3.44 x 10−7 |
Solubility | insoluble in ethanol, alkalis slightly soluble in acids |
Refractive index (nD) |
1.622[2] |
Structure | |
Orthorhombic, oP24 | |
Pnma, No. 62[3] | |
Thermochemistry | |
Std molar entropy (S |
117.0 J·mol−1·K−1 |
Std enthalpy of formation (ΔfH |
-1453.1 kJ·mol−1 |
Hazards | |
Safety data sheet | External MSDS data |
NFPA 704 | |
Flash point | Non-flammable |
Related compounds | |
Other anions |
Strontium chloride Strontium oxide |
Other cations |
Beryllium sulfate Magnesium sulfate Calcium sulfate Barium sulfate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
verify (what is ?) | |
Infobox references | |
Strontium sulfate (SrSO4) is the sulfate salt of strontium. It is a white crystalline powder and occurs in nature as the mineral celestine. It is poorly soluble in water to the extent of 1 part in 8,800. It is more soluble in dilute HCl and nitric acid and appreciably soluble in alkali chloride solutions (e.g. sodium chloride).
Structure
Strontium sulfate is a polymeric material, isostructural with barium sulfate. Crystallized strontium sulfate is utilized by a small group of radiolarian protozoa, called the Acantharea, as a main constituent of their skeleton.
Applications
Strontium sulfate is of interest as a naturally occurring precursor to other strontium compounds, which are more useful. In industry it is converted to the carbonate for use as ceramic precursor and the nitrate for use in pyrotechnics.[4]
References
- ↑ Lide, David R. (1998). Handbook of Chemistry and Physics (87 ed.). Boca Raton, FL: CRC Press. pp. 4–87; 1364. ISBN 0-8493-0594-2.
- ↑ Patnaik, Pradyot (2003). Handbook of Inorganic Chemical Compounds. McGraw-Hill. pp. 560–576. ISBN 0-07-049439-8. Retrieved 2009-06-06.
- ↑ Krystek, M. (1979). "Lattice Parameters of (BaxSr100-x)SO4 Doped with Europium". Physica Status Solidi (a). 54 (2): K133. doi:10.1002/pssa.2210540256.
- ↑ J. Paul MacMillan, Jai Won Park, Rolf Gerstenberg, Heinz Wagner, Karl Köhler, Peter Wallbrecht “Strontium and Strontium Compounds” in Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH, Weinheim. doi:10.1002/14356007.a25_321.
Salts and esters of the sulfate ion | |||||||||||||||||||
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H2SO4 | He | ||||||||||||||||||
Li2SO4 | BeSO4 | B | esters ROSO3− (RO)2SO2 |
(NH4)2SO4 N2H6SO4 (NH3OH)2SO4 |
O | F | Ne | ||||||||||||
Na2SO4 NaHSO4 |
MgSO4 | Al2(SO4)3 Al2SO4(OAc)4 |
Si | P | SO42− | Cl | Ar | ||||||||||||
K2SO4 KHSO4 |
CaSO4 | Sc2(SO4)3 | Ti(SO4)2 TiOSO4 |
V2(SO4)3 VOSO4 |
CrSO4 Cr2(SO4)3 |
MnSO4 | FeSO4 Fe2(SO4)3 |
CoSO4, Co2(SO4)3 |
NiSO4 | CuSO4 | ZnSO4 | Ga2(SO4)3 | Ge | As | Se | Br | Kr | ||
RbHSO4 Rb2SO4 |
SrSO4 | Y2(SO4)3 | Zr(SO4)2 | Nb | Mo | Tc | Ru | Rh | PdSO4 | Ag2SO4 | CdSO4 | In2(SO4)3 | SnSO4 | Sb2(SO4)3 | Te | I | Xe | ||
Cs2SO4 | BaSO4 | Hf | Ta | W | Re | Os | Ir | Pt | Au | Hg2SO4, HgSO4 |
Tl2SO4 | PbSO4 | Bi2(SO4)3 | Po | At | Rn | |||
Fr | Ra | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |||
↓ | |||||||||||||||||||
La | Ce2(SO4)3 Ce(SO4)2 |
Pr2(SO4)3 | Nd | Pm | Sm | Eu | Gd | Tb | Dy | Ho | Er | Tm | Yb2(SO4)3 | Lu | |||||
Ac | Th | Pa | U(SO4)2 UO2SO4 |
Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr |