Photodegradation

Photo-degradation is the alteration of materials by light. Typically, the term refers to the combined action of sunlight and air. Photo-degradation is usually oxidation and hydrolysis. Often photodegradation is avoided, since it destroys paintings and other artifacts. It is however partly responsible for remineralization of biomass and is used intentionally in some disinfection technologies. Photodegradation does not apply to how materials may be aged or degraded via Infrared light or heat, but does include degradation in all of the ultravioliet light wavebands.

Where photodegradation is important

Foodstuffs

The protection of food from photodegradation is very important. Some nutrients, like beer for example, are affected by degradation when being exposed to sunlight. In the case of beer, the UV radiation causes a process, which entails the degradation of hop bitter compounds to 3-Methyl-2-buten-1-thiol and therefore changes the taste. As amber glass has the ability to absorb UV radiation, beer bottles are often made from this glass type to avoid this process.

Paints, inks and dyes

Paints, inks and dyes that are organic are more susceptible to photodegradation than those that are not. Ceramics are almost universally coloured with non-organic origin materials so as to allow the material to retain its colour even with the most relentless photo -degradation.

Pesticides & herbicides

The photodegradation of pesticides is of great interest because of the scale of agriculture and the intensive use of chemicals. Pesticides are however selected in part not to photodegrade readily in sunlight in order to allow them to exert their biocidal activity. Thus, additional modalities are implemented to enhance their photodegradation, including the use of photosensitizers, photocatalysts (e.g., titanium dioxide), and the addition of reagents such as hydrogen peroxide that would generate hydroxyl radicals that would attack the pesticides.[1]

Pharmaceuticals

The photodegradation of pharmaceuticals is of interest because they are found in many water supplies. They have deleterious effects on aquatic organisms including toxicity, endocrine disruption, genetic damage.[2] But also in the primary packaging material the photodegradation of pharmaceuticals has to be prevented. For this, amber glasses like FIOLAX® amber are commonly used to protect the pharmaceutical from UV radiations. Iodine (in the form of Lugol's Solution) and collodial silver are universally used in packaging that lets through very little UV light so as to avoid degradation.

Polymers

Effect of UV exposure on polypropylene rope

Common synthetic polymers that can be attacked include polypropylene and LDPE, where tertiary carbon bonds in their chain structures are the centres of attack. Ultraviolet rays interact with these bonds to form free radicals, which then react further with oxygen in the atmosphere, producing carbonyl groups in the main chain. The exposed surfaces of products may then discolour and crack, and in extreme cases, complete product disintegration can occur.

In fibre products like rope used in outdoor applications, product life will be low because the outer fibres will be attacked first, and will easily be damaged by abrasion for example. Discolouration of the rope may also occur, thus giving an early warning of the problem.

Polymers which possess UV-absorbing groups such as aromatic rings may also be sensitive to UV degradation. Aramid fibres like Kevlar, for example, are highly UV-sensitive and must be protected from the deleterious effects of sunlight.

Mechanism of photodegradation

Photodegradation of a plastic bucket used as an open-air flowerpot for some years

Many organic chemicals are thermodynamically unstable in the presence of oxygen, however, their rate of spontaneous oxidation is slow at room temperature. In the language of physical chemistry, such reactions are kinetically limited. This kinetic stability allows the accumulation of complex environmental structures in the environment. Upon the absorption of light, triplet oxygen converts to singlet oxygen, a highly reactive form of the gas, which effects spin-allowed oxidations. In the atmosphere, the organic compounds are degraded by hydroxyl radicals, which are produced from water and ozone.[3]

Photochemical reactions are initiated by the absorption of a photon, typically in the wavelength range 290-700 nm (at the surface of the Earth). The energy of an absorbed photon is transferred to electrons in the molecule and briefly changes their configuration (i.e., promotes the molecule from a ground state to an excited state). The excited state represents what is essentially a new molecule. Often excited state molecules are not kinetically stable in the presence of O2 or H2O and can spontaneously decompose (oxidize or hydrolyze). Sometimes molecules decompose to produce high energy, unstable fragments that can react with other molecules around them. The two processes are collectively referred to as direct photolysis or indirect photolysis, and both mechanisms contribute to the removal of pollutants.

The United States federal standard for testing plastic for photo-degradation is 40 CFR Ch. I (7–1–03 Edition)PART 238

Protection against photodegradation

Photodegradation of plastics and other materials can be inhibited with additives, which are widely used. These additives include antioxidants, which interrupt degradation processes. Typical antioxidants are derivatives of aniline. Another type of additive are UV-absorbers. These agents capture the photon and convert it to heat. Typical UV-absorbers are hydroxy-substituted benzophenones, related to the chemicals used in sunscreen.[4]

See also

References

Citations

  1. ↑ Burrows, H.D.; Canle L, M.; Santaballa, J.A.; Steenken, S. (June 2002). "Reaction pathways and mechanisms of photodegradation of pesticides". Journal of Photochemistry and Photobiology B: Biology. 67 (2): 71–108. doi:10.1016/S1011-1344(02)00277-4.
  2. ↑ Boreen, Anne L.; Arnold, William A.; McNeill, Kristopher (1 December 2003). "Photodegradation of pharmaceuticals in the aquatic environment: A review". Aquatic Sciences. 65 (4): 320–341. doi:10.1007/s00027-003-0672-7.
  3. ↑ Walter Simmler "Air, 6. Photochemical Degradation" in Ullmann's Encyclopedia of Industrial Chemistry 2011, Wiley-VCH, Weinheim.
  4. ↑ Rainer Wolf, Bansi Lal Kaul "Plastics, Additives" in Ullmann's Encyclopedia of Industrial Chemistry 2000, Wiley-VCH, Weinheim.

Sources

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