Aluminium monoiodide

Aluminium monoiodide
Names
IUPAC name Aluminium(I) iodide
Identifiers
CAS Number	29977-41-1
3D model (Jmol)	Interactive image
ChemSpider	4575742
PubChem	5462992
InChI Key: FZZOCDAQJJZXMD-UHFFFAOYSA-M Key: FZZOCDAQJJZXMD-FQOILMFZAA
SMILES [AlH2]I
Properties
Chemical formula	AlI
Molar mass	153.886 g/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Aluminium monoiodide is an aluminium(I) compound with the chemical formula ${\ce {AlI}}$ . It is unstable at room temperature due to dismutation:^[1]

{\ce {6AlI->{Al2I6}+4Al}}

It forms a cyclic adduct ${\ce {Al4I4(NEt3)4}}$ with triethylamine.

References

↑ Dohmeier, Carsten; Loos, Dagmar; Schnöckel, Hansgeorg (1996). "Aluminum(I) and Gallium(I) Compounds: Syntheses, Structures, and Reactions". Angewandte Chemie International Edition in English. 35 (2): 129. doi:10.1002/anie.199601291.

Aluminium compounds

Al(I)

Al(II)

Al(III)

Alums	(NH₄)Al(SO₄)₂ KAl(SO₄)₂ NaAl(SO₄)₂

Organoaluminium(III) compounds	(Al(CH₃)₃)₂ (Al(C₂H₅)₃)₂ Al(CH₂CH(CH₃)₂)₃ Al(C₂H₅)₂Cl Al(C₂H₅)₂CN Al(CH₂CH(CH₃)₂)₂H Al(C₂H₅)₂Cl₂C₂H₅Cl Ti(C₅H₅)₂CH₂ClAl(CH₃)₂

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